Is it possible to send an e-mail programmatically in Magento? Maybe from a controller in a custom module, could you get hold of a template, populate its variables, and send
Absolutely. Here's an example from the Checkout helper:
$mailTemplate = Mage::getModel('core/email_template');
$template = Mage::getStoreConfig('checkout/payment_failed/template', $checkout->getStoreId());
$mailTemplate->setDesignConfig(array('area'=>'frontend', 'store'=>$checkout->getStoreId()))
->sendTransactional(
$template,
Mage::getStoreConfig('checkout/payment_failed/identity', $checkout->getStoreId()),
$recipient['email'],
$recipient['name'],
array(
'reason' => $message,
...
'total' => $total
)
);