You can get the list of system call numbers from user mode in (/usr/include/)sys/syscall.h. The numbers ARE NOT the same as in Linux. The file is autogenerated during XNU build from bsd/kern/syscalls/syscalls.master.
If you use the libsystem_kernel syscall export you can use the numbers as they are. If you use assembly you have to add 0x2000000 to mark them for the BSD layer (rather than 0x1000000, which would mean Mach traps, or 0x3000000, which would mean machine dependent).
To see examples of system call usage in assembly, you can easily disassemble the exported wrappers: x86_64's /usr/lib/system/libsystem_kernel.dylib (or ARM64's using jtool from the shared library cache).
