I understand that node and relationship properties are limited to primitive types or arrays of primitive types. The "Maps" section of the Neo4j 2.1 Reference Card
(Edited)
The reference card is a bit too subtle. The most important word is "literal". In other words, you can only use arbitrarily nested maps and arrays in literals, but you cannot store such things in a node or relationship.
For example, this works:
WITH {name:'Alice', age:38, address:[{city:'London', residential:true}, {city: 'Paris', residential: false} ]} AS x
RETURN x;
But this fails:
CREATE (x {name:'Alice', age:38, address:[{city:'London', residential:true}, {city: 'Paris', residential: false} ]})
RETURN x;