And if so, what is the syntax?
Assume that I want an instance of Foo to be unassociated from all instances of Bar: In SQL it would simply be:
delete
To answer your specific question, no, as far as I'm aware it's not possible with HQL.
I think you're mixing SQL and HQL a little bit here. In SQL, you indeed "delete" records, and of course hibernate will ultimately do that as well. However Hibernate/HQL is designed from an object-oriented mindset, so "delete" in this context means you are deleting objects, not associations. Typically you'd do something like follows:
Foo f = session.get(Foo.class, id);
f.getBars().clear();
session.merge(f);
This retrieves the object by the id you specified, and removes all Bar associations by clearing it's collection. Obviously you have to have the Foo-Bars association mapped in the proper direction for this to work.