Using a microcontroller (PIC18F4580), I need to collect data and send it to an SD card for later analysis. The data it collects will have values between 0 and 1023, or 0x0 a
The obvious solution is not to convert the data to ASCII at all but store it in binary format. That way all you need to worry about is the endianness of the data. If the system performing the later analysis is far more powerful than your embedded target, then it would make sense to let that deal with the conversion and and byte order.
On the other hand, it is possible that the execution time of the / and % is insignificant compared to the time taken to transfer the data to the SD card; so make sure that you are optimising the right thing.