Is there a definitive method of creating either a PDF or a MS Word Doc file within the app and email it immediately (and possibly, also store it).
I have been trying
Unless it is a core feature of your device to create a pdf file I would suggest not to do it yourself. Adding PDF creation is going to be quite a lot of work potentially depending on your performance needs. Java libraries will be easier to add but less performant. Native libraries combined with Java will be more hazzle to maintain build and bug fixing wise.
If you just need to email some information why dont you create a message text in html and use a intent to email it with the build in email program instead? Or if you want you could e.g. put the PDF generation on a server and just email a link..