Good day, sorry for the seemingly broad question title.
I am building an ExtJS4 application using php and sql for the user data. Everything was going fine until one
Not sure about the main question, never seen that before with extjs 4 apps I have written.
For the question in loading the application faster you should be using sencha CMD to produce a concatenated and minified version of your source for using in a production environment.
Edit
I just came across this SO - "Synchronous XMLHttpRequest on the main thread is deprecated" using nodejs app.get or http-server
Talks about the same issue but with a different framework and comments suggests its an error on client side. Have you changed much lately with how your are fetching data from the server?