In the PHP manual of PCRE, http://us.php.net/manual/en/pcre.examples.php, it gives 4 examples of valid patterns:
/<\\/\\w+>/
In fact you can use any non alphanumeric delimiter (excluding whitespaces and backslashes)
"%^[a-z]%"
works as well as
"*^[a-z]*"
as well as
"!^[a-z]!"