Assuming I have a left outer join as such:
from f in Foo
join b in Bar on f.Foo_Id equals b.Foo_Id into g
from result in g.DefaultIfEmpty()
select new { Foo
Improving on Ocelot20's answer, if you have a table you're left outer joining with where you just want 0 or 1 rows out of it, but it could have multiple, you need to Order your joined table:
var qry = Foos.GroupJoin(
Bars.OrderByDescending(b => b.Id),
foo => foo.Foo_Id,
bar => bar.Foo_Id,
(f, bs) => new { Foo = f, Bar = bs.FirstOrDefault() });
Otherwise which row you get in the join is going to be random (or more specifically, whichever the db happens to find first).