root@sclrdev:/home/sclr/certs/FreshCerts# curl --ftp-ssl --verbose ftp://{abc}/ -u trup:trup --cacert /etc/ssl/certs/ca-certificates.crt * About to connect() to {abc
I have solved this problem by adding one line code in cURL script:
curl_setopt($ch, CURLOPT_SSL_VERIFYPEER, false);
Warning: This makes the request absolute insecure (see answer by @YSU)!