Any algorithm exhibits structural recursion on a datatype if basically consists of a switch-statement with a case for each case of the datatype.
for example, when you are working on a type
tree = null
| leaf(value:integer)
| node(left: tree, right:tree)
a structural recursive algorithm would have the form
function computeSomething(x : tree) =
if x is null: base case
if x is leaf: do something with x.value
if x is node: do something with x.left,
do something with x.right,
combine the results
this is really the most obvious way to write any algorith that works on a data structure.
now, when you look at the integers (well, the natural numbers) as defined using the Peano axioms
integer = 0 | succ(integer)
you see that a structural recursive algorithm on integers looks like this
function computeSomething(x : integer) =
if x is 0 : base case
if x is succ(prev) : do something with prev
the too-well-known factorial function is about the most trivial example of
this form.