"yield" would come to my mind. Some of the attributes like [DefaultValue()] are also among my favorites.
The "var" keyword is a bit more known, but that you can use it in .NET 2.0 applications as well (as long as you use the .NET 3.5 compiler and set it to output 2.0 code) does not seem to be known very well.
Edit: kokos, thanks for pointing out the ?? operator, that's indeed really useful. Since it's a bit hard to google for it (as ?? is just ignored), here is the MSDN documentation page for that operator: ?? Operator (C# Reference)
