I have a table:
table votes (
id,
user,
email,
address,
primary key(id),
);
Now I want to make the columns user
You can add multiple-column unique indexes via phpMyAdmin. (I tested in version 4.0.4)
Navigate to the structure page for your target table. Add a unique index to one of the columns. Expand the Indexes list on the bottom of the structure page to see the unique index you just added. Click the edit icon, and in the following dialog you can add additional columns to that unique index.