I am wracking my brains in trying to understand the discrepancy between the font sizes users select or specify (for example, using a FontDialog) and the em-size
there is no pattern in the discrepancy
As you can see, font sizes happen in increments of 0.75.
Edit: You can fine tune sizes if you do not use the font dialog, but the results I suspect will be less pleasing than the 'preferred' sizes.