I have found some mentions in another question of matrix addition being a quadratic operation. But I think it is linear.
If I double the size of a matrix, I need to calc
As you already noted, it depends on your definition of the problem size: is it the total number of elements, or the width/height of the matrix. Which ever is correct actually depends on the larger problem of which the matrix addition is part of.
NB: on some hardware (GPU, vector machines, etc) the addition might run faster than expected (even though complexity is still the same, see discussion below), because the hardware can perform multiple additions in one step. For a bounded problem size (like n < 3) it might even be one step.