Will there be any difference or it\'s just a personal choice?
Mikel explanation is great, it misses just a small fact (which is rather important), it's only one argument being passed including all spaces:
#!
Results in calling:
$ '' path_to_calling_script
So for Example:
$ cat /tmp/test
#!/usr/bin/env python
print "hi"
$ /tmp/test
is the same as calling:
$ /usr/bin/env "python" /tmp/test
The quotes try to show that if you add any flag or other values will be part of the argument being called.
#!/bin/bash -c /bin/env python
Will be interpreted as:
$ /bin/bash "-c /bin/env python"
Which won't work.