C99 adds several useful features to the language, yet I find it difficult to recommend any practice which depends upon C99. The reason for this is because there are few (any?) a
MSVC does not, nor will it probably ever, support C99. But Microsoft has little incentive to update their C compiler. It's not like they will lose much business over it.
But there are plenty of compilers that have support for C99.
http://en.wikipedia.org/wiki/C99#Implementations
Regarding gcc:
http://gcc.gnu.org/c99status.html
You are right that perhaps C99 is not useful for library code (and may never be without Microsoft's support), but if you're working on an in-house or personal project where you can pick the compilers and tools, then the portability is not much of an issue.