It happens in new Xcode7 beta:
CompileAssetCatalog /Users/admin/Library/Developer/Xcode/DerivedData/InstaAd-ddgdnbxlpxipirebpndfmgrxspel/Build/Products/Debug-iph
Sometimes you should uncheck de "alpha" option to export your png images to Xcode. That solve my problem.
Open "Preview" app - File - Export - Uncheck "alpha" option, then replace your old images in Xcode project.