I\'ve been reading about semantic web technologies such as RDF and OWL, and am intrigued about the possibilities of building an RDF / triple-store semantic database on top of my
There are numerous triplestores that use a relational db for the back end.
Check out Apache Jena and openrdf Sesame for triplestores that have both rdbms and "native" (pure triples) backends.
Also, I highly recommend looking at D2RQ which accesses data in your existing relational store through a triplestore overlay.
There are longer lists but those are good starting points.