Recently I made the switch from using asmx web services to using wcf services, the transition is nearly finished, but I know I\'m in for a lot of error checking and testing to m
to name just a few.....
Search Google or Bing for "WCF vs ASMX" and I'm sure you'll find plenty more article, blog posts and comparisons.
ASMX has passed its time - WCF is the present and the future. It can do a lot more - therefore it's a bit more to learn.
But if you check out the right sources, like these two Dotnet Rocks TV shows (Keith Elder Demystifies WCF and Miguel Castro on Extreme WCF), I'm sure you'll get a quick and hopefully painless start into WCF!
Marc