Consider:
struct mystruct_A
{
char a;
int b;
char c;
} x;
struct mystruct_B
{
int b;
char a;
} y;
The sizes of the structur
Structure packing is only done when you tell your compiler explicitly to pack the structure. Padding is what you're seeing. Your 32-bit system is padding each field to word alignment. If you had told your compiler to pack the structures, they'd be 6 and 5 bytes, respectively. Don't do that though. It's not portable and makes compilers generate much slower (and sometimes even buggy) code.