What does it mean to link/unlink something with Homebrew?
It creates a symlink from packages installed in Cellar (regular packages installed with homebrew will already be linked).
What this also does is allow the symlinked installation from Cellar to serve as a dependency for other homebrew installations (if it's required). This is explained in another post.
Also with all homebrew commands you get a description of the formulae with the --help option (e.g. brew link --help
).