Scenario:
Don't try to write your own session scheme, PHP will do it better.
yes you can add more information to your $_SESSION to help prevent session hijacking
for example I generate a fingerprint by combining a secret phrase or random data with the user agent and the session_id() and hash it all. To hijack a session the user would need to figure out a valid session_id, and the hash of the fingerprint. it will look like this. This is a good read
$_SESSION['fingerprint'] = md5('somethingSecret' . $_SERVER['HTTP_USER_AGENT']. session_id());
then you would validate the session like
$check_print = md5('somethingSecret' . $_SERVER['HTTP_USER_AGENT']. session_id());
if($check_print != $_SESSION['fingerprint'] || $_SESSION['authenticated']){
//invalid session
}