We would like to use SAML 2.0 for a Single Sign On solution. As a typical Microsoft shop, we prefer to use Microsoft components as much as possible. Windows Identity Foundation
You should clarify whether you're talking about SAML 2.0 protocol (e.g SAMLP) or just the token type. WIF RTM supports SAML 2.0 tokens, but not SAMLP.
So if it's just SAML 2.0 token support you need, WIF RTM is sufficient, though WIF extensions CTP does add some SAMLP support.
If you're looking for a SAMLP solution and you're a Microsoft shop then you should consider ADFS 2.0.
ADFS 2.0 would do "protocol transition": it will talk SAMLP with the Identity Provider and WS-Federation with your app (both use SAML "Tokens"). WIF supports WS-Federation.