We need to build an administration portal website to support our client/server application. Since we\'re a .Net shop the obvious traditional way would be to do that in ASP.Net.
I would definitely go for a full Silverlight application, specially if you have good experience from WPF. You will be able to reuse your knowledge from WPF, and should be able to pick up Silverlight fairly quickly. I've been working with Silverlight since Beta 1, and the current Beta 2 is of solid quality. I guess it's safe to assume that a RTW version is just around the corner.
Pilf has some valid point, specially around printing. For that I would probably use SQL Reporting Services, or some other reporting framework, on the server side, and then pop up a new window with printable reports. For linking and bookmarking the issues are no different than any other AJAX application. I did a blog post today about how to provide deep linking and back-forward navigation in Silverlight.
Silverlight also has all the hooks needed for great accessibility support, as the UI Automation API from WPF is brought into Silverlight. I don't know if the screen reader vendors have caught up yet. The styling/template support in Silverlight makes it easy to provide high-contrast skins for visual impaired users if that is a concern.