Given the limited sample size (4 suits, 13 different values) I'd just try to match a reference image of the suit and value with a new input image. First find the bounding box of the incoming suit / value (the smallest box enclosing all non-white pixels), scale your reference pictures to match the size of that bounding box, and find the best "match" through pixel-wise absolute difference. The colour of the picture (i.e. red or black) will make this even easier.
