Your Current Code:
$('table').dataTable({
// display everything
"iDisplayLength": -1
});
What you could do:
oTable = $('table').dataTable({
// display everything
"iDisplayLength": -1
});
oTable.fnSort( [ [0,'desc'] ] ); // Sort by first column descending
But as pointed out in the comment below, this may be a cleaner method:
$('table').dataTable({
// display everything
"iDisplayLength": -1,
"aaSorting": [[ 0, "desc" ]] // Sort by first column descending
});