I think a good way to think of it is a classic running Relay Race
Synchronous: Processes like members of the same team, they won't execute until they receive baton (end of the execution of previous process/runner) and yet they are all acting in sync with each other.
Asynchronous: Where processes like members of different teams on the same relay race track, they will run and stop, async with each other, but within same race (overall program execution).
Does it make sense?