There's a category of interview questions that are illegal in some countries, usually pertaining to personal details that are none of the employer's business. That aside, any question is fair game if the interviewer feels it'll help get an idea of the interviewee's capabilities!
If you're hiring for a position that calls for a thinker rather than just a code monkey, it may be useful to throw this kind of problem at the applicant. Who cares if a problem is "well known" to be NP? If the guy is good he'll come to that understanding in analyzing the problem. That may well be the result the interviewer wants to see, or the applicant can go on to do some more pre-analysis and describe how he'd brute-force the problem, or what optimizations he can think to apply to make it more manageable.
