I just asked a question related to how the compiler optimizes certain C++ code, and I was looking around SO for any questions about how to verify that the compiler has performed
Instead of trying to read through an assembler dump, run your program inside a debugger. You can pause execution, single-step through instructions, set breakpoints on the code you want to check, etc. Many debuggers can display your original C code alongside the generated assembly so you can more easily see what the compiler did to optimize your code.
Also, if you are trying to test a specific compiler optimization you can create a short dummy function that contains the type of code that fits the optimization you are interested in (and not much else, the simpler it is the easier the assembly is to read). Compile the program once with optimizations on and once with them off; comparing the generated assembly code for the dummy function between builds should show you what the compiler's optimizers did.