Should every .C or .cpp file should have a header (.h) file for it?
Suppose there are following C files :
Main.C
Func1.C
In general, I don't think there is any explicit relationship between .h and .c files. In many cases (probably most), a unit of code is a library of functionality with a public interface (.h) and an opaque implementation (.c). Sometimes a number of symbols are needed, like enums or macros, and you get a .h with no corresponding .c and in a few circumstances, you will have a lump of code with no public interface and no corresponding .h
in particular, there are a number of times when, for the sake of readability, the headers or implementations (seldom both) are so big and hairy that they end up being broken into many smaller files, for the sake of the programmer's sanity.