You can use stackrel
:
\begin{equation}
2 \stackrel{?}{\le} 3
\end{equation}
\end{document}
Or, if you use the amsmath
package, you can use overset
as follows:
\documentclass{article}
\usepackage{amsmath}
\begin{document}
\begin{equation}
2 \overset{?}{\le} 3
\end{equation}
\end{document}