I have recently installed PostGIS on my Mac (El Capitan 10.11.4, Postgres is version 9.5.1) using Homebrew, and I am following these instructions - http://morphocode.com/how-to-
It often happens to me in OSx, when my system shutdown unexpectedly.
You can just remove the file postmaster.pid.
postmaster.pid
cd Library/Application Support/Postgres/var-{postgres-version}
and remove the postmaster.pid file
restart the Postgres by using this command
pg_ctl -D /usr/local/var/postgres restart