I have recently installed PostGIS on my Mac (El Capitan 10.11.4, Postgres is version 9.5.1) using Homebrew, and I am following these instructions - http://morphocode.com/how-to-
Postmaster is the main PostgreSQL process. You're trying to start PostgreSQL that's already running (and you're saying yourself you can connect to it). Just skip that step of your process.